Even rusting that doesn't involve oxygen?
IIRC when you rust iron in saltwater you get partially water-soluble rust (in contrast to rusting it in freshwater). I always assumed that the soluble part is iron chloride (which is pretty well soluble and supposedly has a matching color of solution), and that you'd still get that in absence of dissolved oxygen. But maybe I'm wrong~~
Hm, I must be wrong. Sodium is much more electronegative than iron, so it's extremely unlikely anything like that would happen (based on my directional intuitions only; I'm very bad at chemistry).
So what the heck is that soluble thing that you get when rusting iron in saltwater?
I remember getting something I believed to be water soluble (maybe I was very silly and was fooled by a very fine suspension?) by leaving a nail in a jar of brine on a radiator for a week. I guess I'll need to reproduce that and make sure (a) I remember everything correctly (b) it's actually a solution.
But what would happen with the sodium?
Ah, right, I confused the direction of electronegativity (I think; you chelate lots of other metals using sodium or potassium salts after all).
Ok, so this should be making the solution basic, so could be easy to disprove.
@robryk @mcc Iron chloride sounds reasonable - the brown stuff in these pics, excess precipitated out and filtered https://thegeoff.net/gr-wp/fractal-filters/