@freemo It appears this 4nm layer is amorphous (or at least polycrystalline), not corundum/sapphire, unless produced by plasma oxidation with the express purpose of producing hardened aluminum oxide for increased hardness. Additionally, while clear, pure, alpha-crystalline aluminum oxide is often called sapphire (for what I think must be a marketing gimmick) it is actually just pure corundum, as sapphire is corundum with the metal ion inclusions that aren't red (which is ruby).
But the aluminum passivity layer is pretty sick from a materials/chemical perspective for sure :3